Bismuth(III) acetate
Nowadays, Bismuth(III) acetate has become a topic of general interest to a large number of people around the world. Its relevance and impact cover multiple aspects of daily life, from health to technology, including politics, culture and the economy. Bismuth(III) acetate is a topic that generates debate and controversy, but also arouses interest and curiosity, which makes it a meeting point for people from different fields and interests. In this article, we will explore in depth the importance and scope of Bismuth(III) acetate, as well as its evolution over time and its influence on today's society.
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| Names | |
|---|---|
| IUPAC name
Bismuth(3+) triacetate
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| Other names
Bismuth(III) acetate; Bismuth triacetate
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.040.806 |
| EC Number |
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PubChem CID
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| UNII | |
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| Properties | |
| Bi(CH3COO)3 | |
| Molar mass | 386.112 g/mol |
| Appearance | White crystals or powder |
| Density | 2.765 g/cm3 |
| hydrolyzes | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).
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Bismuth(III) acetate is the coordination complex with the formula Bi(O2CCH3)3. It is a molecular compound featuring Bi bound to six oxygen ligands in a distorted polyhedral sphere. According to X-ray crystallography, the acetate ligands are bound very unsymmetrically such that three Bi-O bonds are approximately 2.3 Å in length, and three others are near 2.6 Å. The stereochemically active lone pair of electrons occupies significant portion of the coordination sphere.[1] The compound has been further characterized by solid-state NMR spectroscopy.[2]
Bismuth(III) acetate will hydrolyze to form basic bismuth acetate precipitates. This reaction is useful to separate lead and bismuth.[3]
- Bi(CH3COO)3 + H2O → BiOCH3COO + 2 CH3COOH
See also
References
- ^ Troyanov, S. I.; Pisarevskii, A. P. (1991). "Crystal Structure of Bismuth(3+) Acetate". Koordinatsionnaya Khimiya. 17: 909-13.
- ^ Hamaed, Hiyam; Laschuk, Michael W.; Terskikh, Victor V.; Schurko, Robert W. (2009). "Application of Solid-State 209Bi NMR to the Structural Characterization of Bismuth-Containing Materials". Journal of the American Chemical Society. 131 (23): 8271–8279. doi:10.1021/ja901347k. PMID 19462954.
- ^ Benkert, Arthur L.; Smith, Edgar F. (1896). "The Separation of Bismuth from Lead". Journal of the American Chemical Society. 18 (12): 1055–1056. doi:10.1021/ja02098a005. ISSN 0002-7863.
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