Rhenium dioxide trifluoride
Rhenium dioxide trifluoride is a topic that has generated interest and debate in recent years. Known for its relevance in different aspects of society, this topic has captured the attention of experts and people interested in understanding its impact. As you delve deeper into Rhenium dioxide trifluoride, new perspectives and questions arise that invite you to explore its many facets. This article seeks to offer a comprehensive view of Rhenium dioxide trifluoride, addressing everything from its origins to its current implications. Through a detailed analysis and enriching reflections, it is intended to provide the reader with a broader and more enriching look at Rhenium dioxide trifluoride.
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| Identifiers | |
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3D model (JSmol)
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| Properties | |
| F3O2Re | |
| Molar mass | 275.200 g·mol−1 |
| Appearance | white |
| Density | 5.161 g/cm3 |
| Melting point | 35 °C; 95 °F; 308 K |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).
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Rhenium dioxide trfluoride is an inorganic compound with the formula ReO2F3. A white diamagnetic solid, it one of the few oxyfluorides of rhenium, another being rhenium trioxide fluoride, ReO3F. The material is of some academic interest as a rare example of an dioxide trifluoride.[1] It can be prepared by the reaction of xenon difluoride and rhenium trioxide chloride:
- 2 ReO3Cl + 3 XeF2 → 2 ReO2F3 + O2 + Cl2 + 3 Xe
According to X-ray crystallography, the compound can exist in four polymorphs. Two polymorphs adopt chain-like structures featuring octahedral Re centers linked by bridging fluorides. Two other polymorphs adopt cyclic structures (ReO2F3)3 and (ReO2F3)4, again featuring octahedral Re centers and bridging fluorides. Like related oxyfluorides, these coordination oligomers break up in the presence of Lewis bases. Adducts of the formula ReO2F3L where L = acetonitrile have been crystallized.[2]
References
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. doi:10.1016/C2009-0-30414-6. ISBN 978-0-08-037941-8.
- ^ Supeł, Joanna; Marx, Rupert; Seppelt, Konrad (2005). "Preparation and Structure of Rhenium Fluoride Trioxide ReO3F, and the Polymorphism of Rhenium Trifluoride Dioxide, ReO2F3". Zeitschrift für anorganische und allgemeine Chemie. 631 (15): 2979–2986. doi:10.1002/zaac.200500239.